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Regioselective Acylation of Cyclic α‐Silylallyl Sulphide
Author(s) -
Chen LingChing,
Chen LihMing,
Lin LihHom
Publication year - 1984
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.198400059
Subject(s) - chemistry , acylation , regioselectivity , halide , yield (engineering) , selectivity , chloride , aluminium , organic chemistry , acyl chloride , medicinal chemistry , catalysis , materials science , metallurgy
Acylation of cyclic α‐trimethylsilylallyl sulphide ( 3 ) by reaction with the acid halide catalyzed by aluminum chloride in CH 2 Cl 3 at −78° C gave compound 4 in good yield with extremely high regio‐selectivity.