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Thermodynamic Studies on the Complexation Reactions of Copper(II) Complex of o 2 n 2 ‐Donor Macrocycle with Halide and Pseudohalide Ions
Author(s) -
Wang Bind,
Lin YiJen,
Chung ChungSun
Publication year - 1983
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.198300032
Subject(s) - chemistry , halide , copper , methanol , ion , inorganic chemistry , organic chemistry
Complexation reactions of 5,6,7,8,9,10,16,17‐octahydrodibenzo[ e, m ][1, 4]dioxa‐[8, 11]diazacyclotetradecine‐copper(II) complex with halide and pseudohalide ions have been studied at 25.0° in three water‐methanol mixed solvents by spectro‐photometric method. It is found that the equilibrium constants increases in the order of 50 vol.% CH 3 OH<75 vol.% CH 3 OH<95 vol.% CH 3 OH for solvents and I‐