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Lanthanon (III) Derivatives of Monofunctional Bidentate Schiff Bases
Author(s) -
Gharia K. S.,
Mathur Miss Shakuntala,
Singh Megh,
Sankhla B. S.
Publication year - 1980
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.198000021
Subject(s) - chemistry , denticity , schiff base , toluidine , polymer chemistry , infrared spectroscopy , ion , medicinal chemistry , stereochemistry , crystallography , organic chemistry , crystal structure
The 1:1, 1:2 and 1:3 interactions of lanthanon (III) isopropoxide with monofunctional bidentate Schiff bases as salicylidene‐ o ‐toluidine (SOTH) and salicylidene‐ p ‐p‐toluidine (SPTH) have been investigated. The resulting products Ln(OPr 1 ) 2 (SB), Ln(OPr 1 )(SB) 2 and Ln(SB) 3 (where Ln=Pr, Nd and Sm and SB 1− is the anion of the corresponding Schiff base) have been isolated in almost quantitative yields. The infrared spectra of these compounds have been recorded and plausible structures suggested.