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Complexes of Cobalt(II), Nickel(II) and Copper(II) Chloroacetates with Quinoline N‐Oxide
Author(s) -
Kumar N.,
Kachroo P. L.,
Gandotra A. K.,
Kant Rama
Publication year - 1980
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.198000006
Subject(s) - chemistry , quinoline , adduct , stoichiometry , nickel , cobalt , copper , metal , inorganic chemistry , oxide , nuclear chemistry , polymer chemistry , organic chemistry
Some 1:1 and 1:2 adducts of cobalt(II), nickel(II) and copper(II) chloroacetates with quinoline N ‐oxide have been isolated by the interaction of the appropriate metal chloroacetate with quinoline N ‐oxide (QuinNo). The complexes isolated are of 1:1 stoichiometry of formula [M(CH 3 _xClxCOO) 2 QuinNO] (when M=Co(II), Ni(II); X=1,2 and 3 and when M=Cu(II), X=l and 2) except copper(II) trichloroacetate which yields an adduct of 1:2 stoichiometry of formula[Cu(CCI 3 COO) 2 (QuinNO) 2 ]. The adducts isolated are soluble in common organic solvents.