Quantitative Estimation of Ruthenium(III) Using Morpholine‐4‐Carbodithioate as a New Analytical Reagent | Zendy

Kumar Ravindra | Zendy; Singh Nepal | Zendy; Kansal B. D. | Zendy

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Quantitative Estimation of Ruthenium(III) Using Morpholine‐4‐Carbodithioate as a New Analytical Reagent

Author(s) -

Kumar Ravindra,

Singh Nepal,

Kansal B. D.

Publication year - 1979

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.197900017

Subject(s) - chemistry , ruthenium , morpholine , reagent , tartrate , metal , inorganic chemistry , molar ratio , metal ions in aqueous solution , nuclear chemistry , ion , organic chemistry , catalysis

Ruthenium(III) has been precipitated gravimetrically in the pH range 7.0‐8.5 with morpholine‐4‐carbodithioate and determined by weighing as a black complex (C 5 H 6 ONS 2 ) 3 Ru after drying at l00–110°C. The interference of the various metal ions has been avoided by using an ammonical mixture of EDTA and tartrate (1:1 molar ratio). The complex is thermally stable up to l60°C.

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