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Salicylate of Uranium
Author(s) -
Dubey S.,
Hasan M.,
Kapoor R. N.
Publication year - 1978
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.197800019
Subject(s) - chemistry , uranyl , uranium , salicylic acid , stoichiometry , nuclear chemistry , medicinal chemistry , inorganic chemistry , ion , organic chemistry , biochemistry , materials science , metallurgy
The reactions of uranium pentaethoxide with salicylic acid have been carried out in different stoichiometric ratios, yielding products of the type, U(OEt) 3 (C 7 H 4 O 3 ), U(OEt)(C 7 H 4 O 3 ) 2 , U(C 7 H 4 O 2 ) 2 (C 7 H 4 O 3 ), and U 2 (C 7 H 4 O 3 ) 3 . A detailed study of the complexation reactions of uranyl ion with salicylic acid have also been made by potentiomertic and conductometric methods. The formation of 1:1 and 1:2 complexes have been confirmed by preparative studies. Two compounds, viz. (C 5 H 6 N) 2 UO 2 (C 7 H 4 O 3 ) 2 (NH 4 ) 2 UO 2 (C 7 H 4 O 3 ) 2 have been isolated.
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