Study on the Silylation of Aromatic Hydrocarbons. The Trimethylsilylation of Naphthalene | Zendy

Yang MeiHui | Zendy; Liu MoonLan | Zendy; Liu ShengLieh | Zendy

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Study on the Silylation of Aromatic Hydrocarbons. The Trimethylsilylation of Naphthalene

Author(s) -

Yang MeiHui,

Liu MoonLan,

Liu ShengLieh

Publication year - 1978

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.197800012

Subject(s) - trimethylsilyl , chemistry , silylation , naphthalene , tris , organic chemistry , medicinal chemistry , catalysis , biochemistry

Direct trimethylsilylation of naphthalene under certain condition has been found to afford substitution as well as addition products: 1‐and 2‐trimethylsilylnaphtalene (I, II), 1‐trimethylsilyl‐1,4‐dihydronaphthalene (III), trans‐1,2‐bis(trimethylsilyl)‐1,2‐dihydronaphthalene (IV‐a) and its isomer (IV‐b), and 1,2,4‐tris(trimethylsilyl)‐1,2‐dihydronaphthalene (V). The configuration has been determined by nmr spectroscopy, and the possible reaction path was proposed.

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