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Studies on the Cotelomerization of Ethylene and Vinyl Chloride with Carbon Tetrachloride
Author(s) -
Wu ChengChing,
Hsu KueiHsien
Publication year - 1976
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.197600013
Subject(s) - chemistry , carbon tetrachloride , ethylene , vinyl chloride , amine gas treating , chloride , salt (chemistry) , tetrachloride , polymer chemistry , carbon fibers , carbon 13 nmr , organic chemistry , inorganic chemistry , catalysis , copolymer , composite number , materials science , tin , composite material , polymer
The cotelomerization of ethylene and vinyl chloride with carbon tetrachloride was studied under various reaction conditions by using the amine‐metallic salt initiating system. From the GC and NMR spectra, we found that no cotelomerization occured. This is contrary to the findings determined by Rosin et al. The modified insertion mechanism proposed by Asahada and Wu was used to explain the experimental results.