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Studies on the Preparation and Properties of Thiol Derivatives of Biscyclopentadienyl Molybdenum (VI) and Bisindenyl Molybdenum (VI) Oxide Dichloride
Author(s) -
Bhalla M. S.,
Multani R. K.
Publication year - 1976
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.197600006
Subject(s) - chemistry , molybdenum , tetrahydrofuran , molybdenum oxide , oxide , thiol , inorganic chemistry , infrared spectroscopy , nuclear chemistry , organic chemistry , solvent
Biscyclopentadienyl molybdenum (VI) oxide dichloride (I) and bisindenyl molybdenum (VI) oxide dichloride (II) react with various thiols in tetrahydrofuran and from the complexes of the type (C 3 H 5 ) 2 MoO (R 2 ) and (C 9 H 7 ) 2 MoO (R 2 ) wherein R may be S CH 8 , S C 2 H 5 , S C 3 H N 7 , S C 3 H 7 , S C 4 H n 9 , or S C 4 H 3 or S C 3 H 11 . The preparation, thermal stabilities, physical characteristics and infrared spectra of these complexes have been studied in this paper.