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Correlation of Mössbauer and Radiochemical Data on Hexacyanoferrate(III)
Author(s) -
Lee Y. J.,
Chen J. W.,
Huang C. H.,
Yeii S. J.,
Cheng H. S.
Publication year - 1974
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.197400004
Subject(s) - prussian blue , chemistry , irradiation , mössbauer spectroscopy , nuclear chemistry , spectral line , radiochemistry , inorganic chemistry , analytical chemistry (journal) , crystallography , chromatography , electrochemistry , nuclear physics , physics , electrode , astronomy
Mössbauer spectra of irradiated K 1 Fe(CN) 6 , observed 3 weeks after irradiation, showed that 3% of iron was converted to Fe(CN) 6 4− , while chemical analysis performed 100 hours after irradiation showed 18% was reduced to Fe(CN) 6 4− , Prussian blue was isolated in the chemical analysis, but not observed in the Mössbauer spectra. The Prussian blue formation was found to be time dependent.