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Triorganosilyl Ethers of Benzaldehyde, m ‐Methoxybenzaldehyde and Anisoles
Author(s) -
Liu ShengLieh,
Wu RsienJen,
Wu WenJen,
Chu YuanChieh,
Lee GuoJen
Publication year - 1973
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.197300023
Subject(s) - chemistry , benzaldehyde , benzene , group (periodic table) , ring (chemistry) , medicinal chemistry , ether , linkage (software) , stereochemistry , organic chemistry , catalysis , biochemistry , gene
Synthesis of six new triorganosiloxybenzaldehydes, two m ‐methoxy‐(triorganosiloxy)benzaldehydes, and seven methoxy(triorganosiloxy)benzenes are reported. From comparison of the stability of these compounds in the atmosphere, it is concluded that formyl group shows unfavorable influence and methoxy group shows favorable influence on the stability of these compounds. The oposite influences of these two groups on phenoxysilane linkage seems to connect with the oposite directiones of inductive effect of formyl group and resonance effect of methoxy group on the benzene ring.