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Studies on Carboxylato Complexes of Tricyclopentadienyl Cerium (IV) Chloride and Bisindenyl Cerium (IV) Dichloride
Author(s) -
Kalsotra B. L.,
Multani R. K.,
Jain B. D.
Publication year - 1971
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.197100023
Subject(s) - chemistry , cerium , tetrahydrofuran , benzene , chloride , sodium , medicinal chemistry , inorganic chemistry , nuclear chemistry , organic chemistry , solvent
Tricyclopentadienyl Cerium (IV) chloride and bisindenyl cerium (IV) dichloride have been treated with sodium salts of the appropriate carboxylic acids in benzene or tetrahydrofuran medium to give (C 5 H 3 ) 3 Ce(R) and (C 9 H 7 ) 2 Ce(R) 2 wherein R is HCOO, CH 3 COO, C 2 H 5 COO, C 3 H 7 COO and C 6 H 5 COO. The infrared spectra, thermal stabilities and other characteristics of the above compounds have been studied and reported.