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Cathodic Action of the Metal Complexes at the Dropping Mercury Electrode. VIII. Uranyl‐Glycinate Complex
Author(s) -
Lai TsaiTeh,
Lin HanTon,
Hsieh ChingChiang
Publication year - 1963
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.196300004
Subject(s) - chemistry , polarography , uranyl , chelation , dropping mercury electrode , cathodic protection , inorganic chemistry , mercury (programming language) , metal , electrode , metal ions in aqueous solution , ion , electrochemistry , organic chemistry , computer science , programming language
The formation of complex between uranyl ion and glycine was investigated by the polarographic method. A reversible and diffusion controlled reduction waves were observed over the p H range 1.7 to 5.0 when the glycinate concentration was 0.049 M to 0.393 M . The effect of p H and the concentration of chelating agent on the half‐wave potential has been determined. The chelate species and the electrode reactions have been established.