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Note on the Evaluation of the ϵ′ Folding Energy by Stress‐Temperature Measurements
Author(s) -
Shen Mitchel C.
Publication year - 1962
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.196200016
Subject(s) - chemistry , constant (computer programming) , thermodynamics , term (time) , folding (dsp implementation) , extension (predicate logic) , stress (linguistics) , energy (signal processing) , statistics , structural engineering , quantum mechanics , linguistics , philosophy , physics , mathematics , computer science , engineering , programming language
A further refinement in the evaluation of ϵ′ folding energy 13 presented. It is found that a correction term R3TT 2 /(a 3 —1) should be included into a previously derived equation, if ϵ′ is determined by stress‐temperature measurements at constant pressure and constant extended length. The results confirms quantitatively our previous estimation that when relative extension ratio is greater than 1.5, the correction term is negligible.