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Kinetic Studies of the Alkaline Hydrolysis of Alkyl Acetates by Conductometric Measurements
Author(s) -
Pan Kuan,
Chang ChenFee,
Hong HuiShong
Publication year - 1962
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.196200011
Subject(s) - chemistry , alkaline hydrolysis , hydrolysis , sodium hydroxide , conductometry , alkyl , kinetic energy , hydroxide , inorganic chemistry , sodium , activation energy , organic chemistry , physics , quantum mechanics
Reaction rates for the alkaline hydrolysis of methyl‐, ethyl‐, n ‐propyl‐ and n ‐butyl acetates in the presence of 0.01 N sodium hydroxide solution at 15°, 20°, 25°, 30° and 35°C were followed directly by conductometric measurements of the reacting system. The energies and entropies of activation for these reactions were estimated.