Lithium Aryls. I. Preparation of  p ‐Cyclohexenyl‐Phenyllithium by Halogen‐Lithium Interconversion Reaction | Zendy

Chang Daniel Y. | Zendy; Yu RueyJiin | Zendy

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Lithium Aryls. I. Preparation of p ‐Cyclohexenyl‐Phenyllithium by Halogen‐Lithium Interconversion Reaction

Author(s) -

Chang Daniel Y.,

Yu RueyJiin

Publication year - 1961

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.196100009

Subject(s) - phenyllithium , chemistry , organolithium compounds , lithium (medication) , butyllithium , halogen , cyclohexene , organic chemistry , medicinal chemistry , ion , catalysis , medicine , alkyl , deprotonation , endocrinology

The halogen‐lithium interconversion reaction between p ‐bromophenyl‐cyclohexene‐1 and organolithium compounds was investigated. It resulted in the production of p ‐Δ 1 ‐cyclohexenyl‐phenyllithium. The organolithium compounds used in the interconversion reaction were phenyllithium, n ‐propyllithium and n ‐butyllithium. They brought about 25%, 19% and 10% conversions based on p ‐bromophenylcyclohexene‐1 respectively.

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