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The Oxidation of α, β‐Unsaturated Cyclic Acids by NaIO 4 ‐KMnO 4 Couple and KMnO 4
Author(s) -
Lin YauTang,
Cheng YuShia
Publication year - 1960
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.196000014
Subject(s) - chemistry , cycloheptene , cyclopentene , cyclohexene , adipic acid , succinic acid , carboxylic acid , halogenation , organic chemistry , glutaric acid , catalysis
1‐Cyclopentene carboxylic acid (I), 1‐cyclohexene carboxylic acid and (II), and 1‐cycloheptene carboxylic acid (III) were oxidized with NaIO 4 ‐KMnO 4 couple and acidic KMnO 4 . From I succinic acid was the main product and glutaric acid was the minor product. But in the case of II and III, the main products were adipic acid and pimelic acid respectively. Qualitatively there was no difference between NaIO 4 ‐KMnO 4 couple and acidic KMnO 4 oxidation.