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On the Synthesis of Hydroterphenyl Derivatives by Grignard Reaction
Author(s) -
Chang Daniel Y.,
Shieh Nan
Publication year - 1954
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.195400007
Subject(s) - chemistry , cyclohexanone , grignard reaction , dehydration , bromide , medicinal chemistry , alcohol , organic chemistry , dehydration reaction , tertiary alcohols , reagent , catalysis , biochemistry
Abstract The reaction between p‐bromophenylmagnesium bromide and cyclo‐h‐exanone has been reinvestigated. p‐Bromophenylcyclohexene (tetrahydro‐p‐bromodiphenyl), dehydration product of the tertiary alcohol resulted from the above reaction, was converted into the corresponding organomagnesium compound by a special method. The latter was in turn allowed to react with cyclohexanone, resulting in the formation of hydroterphenyl derivatives.