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Effects of multidimensional tunneling in the kinetics of hydrogen abstraction reactions of O ( 3 P) with CH 3 OCHO
Author(s) -
de Carvalho E. F. V.,
RobertoNeto O.
Publication year - 2018
Publication title -
journal of computational chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.907
H-Index - 188
eISSN - 1096-987X
pISSN - 0192-8651
DOI - 10.1002/jcc.25211
Subject(s) - quantum tunnelling , hydrogen atom abstraction , reaction rate constant , enthalpy , chemistry , hydrogen , potential energy surface , atmospheric temperature range , curvature , atomic physics , kinetics , transition state theory , range (aeronautics) , molecule , activation energy , computational chemistry , thermodynamics , physics , materials science , quantum mechanics , mathematics , geometry , organic chemistry , composite material
Quantum tunneling paths are important in reactions when there is a significant component of hydrogenic motion along the potential energy surface. In this study, variational transition state with multidimensional tunneling corrections are employed in the calculations of the thermal rate constants for hydrogen abstraction from the cis‐ CH 3 OCHO by O ( 3 P) giving CH 3 OCO + OH (R1) and CH 2 OCHO + OH (R2). The structures and electronic energies are computed with the M06‐2X method. Benchmark calculations with the CBS D–T approach give an enthalpy of reaction at 0 K for R1 (−2.8 kcal/mol) and R2 (−2.5 kcal/mol) which are in good agreement with the experiment, i.e. −2.61 and −1.81 kcal/mol. At the low and intermediate values of temperatures, small‐ and large‐curvature tunneling dominate the kinetics of R1, which is the dominant path over the range of temperature from 250 to 1200 K. This study shows the importance of multidimensional tunneling corrections for both R1 and R2, for which the total rate constant at 298 K calculated with the CVT/ μ OMT method is 8.2 × 10 −15 cm 3 molecule −1 s −1 which agrees well with experiment value of 9.3 × 10 −15 cm 3 molecule −1 s −1 (Mori, Bull. Inst. Chem. Res. 1981, 59, 116). © 2018 Wiley Periodicals, Inc.