Premium
A QTAIM and stress tensor investigation of the torsion path of a light‐driven fluorene molecular rotary motor
Author(s) -
Hu Ming Xing,
Xu Tianlv,
Momen Roya,
Huan Guo,
Kirk Steven R.,
Jenkins Samantha,
Filatov Michael
Publication year - 2016
Publication title -
journal of computational chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.907
H-Index - 188
eISSN - 1096-987X
pISSN - 0192-8651
DOI - 10.1002/jcc.24487
Subject(s) - torsion (gastropod) , scalar (mathematics) , physics , tensor (intrinsic definition) , classical mechanics , mathematics , geometry , medicine , surgery
The utility of the QTAIM/stress tensor analysis method for characterizing the photoisomerization of light driven molecular rotary machines is investigated on the example of the torsion path in fluorene molecular motor. The scalar and vector descriptors of QTAIM/stress tensor reveal additional information on the bonding interactions between the rotating units of the motor, which cannot be obtained from the analysis of the ground and excited state potential energy surfaces. The topological features of the fluorene motor molecular graph display that, upon the photoexcitation a certain increase in the torsional stiffness of the rotating bond can be attributed to the increasing topological stability of the rotor carbon atom attached to the rotation axle. The established variations in the torsional stiffness of the rotating bond may cause transfer of certain fraction of the torsional energy to other internal degrees of freedom, such as the pyramidalization distortion. © 2016 Wiley Periodicals, Inc.