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Stability of ion triplets in ionic liquid/lithium salt solutions: Insights from implicit and explicit solvent models and molecular dynamics simulations
Author(s) -
Eilmes Andrzej,
Kubisiak Piotr
Publication year - 2015
Publication title -
journal of computational chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.907
H-Index - 188
eISSN - 1096-987X
pISSN - 0192-8651
DOI - 10.1002/jcc.23853
Subject(s) - molecular dynamics , solvation , ionic liquid , chemistry , ion , polarizability , chemical physics , quantum chemical , solvent , solvent models , ionic bonding , computational chemistry , lithium (medication) , quantum , quantum chemistry , thermodynamics , molecule , physics , quantum mechanics , organic chemistry , medicine , endocrinology , catalysis
Binding energies of ion triplets formed in ionic liquids by Li + with two anions have been studied using quantum‐chemical calculations with implicit and explicit solvent supplemented by molecular dynamics (MD) simulations. Explicit solvent approach confirms variation of solute‐ionic liquid interactions at distances up to 2 nm, resulting from structure of solvation shells induced by electric field of the solute. Binding energies computed in explicit solvent and from the polarizable continuum model approach differ largely, even in sign, but relative values generally agree between these two models. Stabilities of ion triplets obtained in quantum‐chemical calculations for some systems disagree with MD results; the discrepancy is attributed to the difference between static optimized geometries used in quantum chemical modeling and dynamic structures of triplets in MD simulations. © 2015 Wiley Periodicals, Inc.