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Effects of packaging environments on free radicals in γ‐irradiated UHMWPE resin powder blend with vitamin E
Author(s) -
Ridley M. D.,
Jahan M. S.
Publication year - 2008
Publication title -
journal of biomedical materials research part a
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.849
H-Index - 150
eISSN - 1552-4965
pISSN - 1549-3296
DOI - 10.1002/jbm.a.32042
Subject(s) - radical , electron paramagnetic resonance , materials science , irradiation , polyethylene , fourier transform infrared spectroscopy , nuclear chemistry , spectroscopy , polymer chemistry , photochemistry , chemical engineering , composite material , organic chemistry , chemistry , nuclear magnetic resonance , physics , quantum mechanics , nuclear physics , engineering
Abstract Ultra‐high molecular weight polyethylene (UHMWPE) powder (GUR 1020) was blended with high concentration (20%) of vitamin E (α‐Tocopherol (α‐T)) for direct detection of α‐T radicals in presence of PE radicals. Samples were γ‐irradiated in sealed packages filled with N 2 , or in open air. Free radicals were measured in open air environment for 71 days using electron spin resonance (ESR) technique. When irradiated in air, both α‐T and α‐T‐resin produced identical ESR signals characteristics of tochopheroxyl radicals (α‐T‐O • ), suggesting that PE radicals are quenched by α‐T. There was no indication of growth of oxygen‐induced radicals (OIR) either. However, when α‐T‐resin was irradiated in N 2 , presence of both PE and α‐T radicals were evident in the ESR spectra. And, OIR were produced by the same samples when they were subsequently exposed to air (for 71 days). Oxidation data recorded 85 days after postirradiation aging in air using Fourier transform infra‐red (FTIR) spectroscopy, however, did not show any measurable difference between samples irradiated in N 2 and air. © 2008 Wiley Periodicals, Inc. J Biomed Mater Res, 2009