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Interfacial chemistry of class II composite restoration: Structure analysis
Author(s) -
Wang Yong,
Spencer Paulette
Publication year - 2005
Publication title -
journal of biomedical materials research part a
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.849
H-Index - 150
eISSN - 1552-4965
pISSN - 1549-3296
DOI - 10.1002/jbm.a.30451
Subject(s) - dentin , gingival margin , materials science , adhesive , molar , composite number , dentistry , raman spectroscopy , composite material , layer (electronics) , optics , medicine , physics
The gingival margins of class II composite restorations are particularly vulnerable to marginal leakage and secondary caries. In identifying the factors contributing to caries development, the molecular structure and differences in the structure at the proximal and gingival margins have been largely overlooked. The purpose of this study was to compare the molecular structure at the adhesive/dentin interface of the proximal and gingival walls of class II composite restorations. Class II preparations were cut in 12 unerupted third molars with a water‐cooled high‐speed dental handpiece. The prepared teeth were randomly selected for treatment with Single Bond (SB) + Z100 (3M). Teeth were restored, per manufacturer's directions, under humidity and temperature characteristic of the oral cavity. Restored teeth were kept in sterile Delbecco's phosphate saline for 48 h. The samples were sectioned occluso‐gingivally and micro‐Raman spectra were acquired at ∼1.5‐μm spatial resolution across the composite/adhesive/dentin interfaces. Samples were wet throughout spectral acquisition. Raman spectral characteristics at the proximal and gingival margins were distinctly different; the depth of demineralized dentin was 6–7 μm at proximal margin, 12–13 μm at gingival margin. SB adhesive penetrated the depth of demineralized dentin in a gradient at the proximal margin. The “single bottle” adhesive used in this study, gradually penetrated the depth of the demineralized dentin at the proximal margin but failed to infiltrate the depth at the gingival margin, leaving a thick exposed collagen layer. © 2005 Wiley Periodicals, Inc. J Biomed Mater Res, 2005