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DETERMINATION OF ETHANOL IN BEER BY DIRECT INJECTION GAS CHROMATOGRAPHY: A COMPARISON OF SIX IDENTICAL SYSTEMS
Author(s) -
CLARKSON S. P.,
ORMROD I. H. L.,
SHARPE F. R.
Publication year - 1995
Publication title -
journal of the institute of brewing
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.523
H-Index - 51
eISSN - 2050-0416
pISSN - 0046-9750
DOI - 10.1002/j.2050-0416.1995.tb00861.x
Subject(s) - repeatability , reproducibility , chromatography , gas chromatography , ethanol , chemistry , ethanol content , analytical chemistry (journal) , biochemistry
Six identical gas chromatographic (GC) systems from the same manufacturer were evaluated for the determination of ethanol in beers. Each system was assessed for detector linearity and drift using standard ethanol solutions. Repeatability (r 95 ) of each machine, repeatability (r 95 ) of the GC method and reproducibility (R 95 ) of the method over a range of ethanol concentrations (1–11% V/V) was determined using commercial beers. All six instruments were linear over the ethanol range 0–12% V/V and were in good agreement. Drift of the machines was negligible over the period of the analysis. Over the ethanol range 0.95 to 6.32% V/V the repeatability (r 95 ) and reproducibility (R95) values were 0.050 and 0.083 respectively. Over the ethanol range 9.48 to 11.15% V/V the repeatability (r 95 ) and reproducibility (R 95 ) values were 0.153 and 0.227 respectively. Comparison of the precision values and those obtained in a recent IOB Analysis Committee Collaborative 1 for the determination of ethanol by gas chromatography showed no significant differences between the two methods. The reported method is suitable for determination of ethanol in beers.