Open AccessA sound velocity method for determining isobaric specific heat capacity
Author(s) -
Pei Jun,
Li Hezhang,
Zhuang HuaLu,
Dong Jinfeng,
Cai Bowen,
Hu Haihua,
Li JingWei,
Jiang Yilin,
Su Bin,
Zhao LiDong,
Li JingFeng
Publication year - 2022
Publication title -
infomat
Language(s) - English
Resource type - Journals
ISSN - 2567-3165
DOI - 10.1002/inf2.12372
Subject(s) - isobaric process , heat capacity , repeatability , thermoelectric effect , speed of sound , thermodynamics , specific heat , lattice vibration , differential scanning calorimetry , materials science , lattice (music) , vibration , physics , mathematics , acoustics , condensed matter physics , statistics , phonon
Isobaric specific heat capacity ( C p ) is an important parameter not only in physics but also for most materials. Its accurate measurement is particularly critical for performance evaluation of thermoelectric materials, but the experiments by differential scanning calorimetry (DSC) often lead to large uncertainties in the measurements, especially at elevated temperatures. In this study, we propose a simple method to determine C p by measuring the sound velocity ( υ ) based on lattice vibration and expansion theory. The relative standard error of the υ is smaller than 1%, showing good accuracy and repeatability. The calculated C p at elevated temperature (>300 K) increases slightly with increasing temperature due to the lattice expansion, which is more reasonable than the Dulong–Petit value.