Open AccessInterface issues of lithium metal anode for high‐energy batteries: Challenges, strategies, and perspectives
Author(s) -
Han Yiyao,
Liu Bo,
Xiao Zhen,
Zhang Wenkui,
Wang Xiuli,
Pan Guoxiang,
Xia Yang,
Xia Xinhui,
Tu Jiangping
Publication year - 2021
Publication title -
infomat
Language(s) - English
Resource type - Journals
ISSN - 2567-3165
DOI - 10.1002/inf2.12166
Subject(s) - anode , faraday efficiency , materials science , electrolyte , energy storage , nanotechnology , electrochemistry , lithium (medication) , energy density , electrode , engineering physics , chemistry , engineering , power (physics) , medicine , physics , quantum mechanics , endocrinology
Lithium (Li) metal is considered as one of the most promising anode materials for next‐generation high‐energy‐density storage systems. However, the practical application of Li metal anode is hindered by interfacial instability and air instability due to the highly reactivity of Li metal. Unstable interface in Li metal batteries (LMBs) directly dictates Li dendrite growth, “dead Li” and low Coulombic efficiency, resulting in inferior electrochemical performance of LMBs and even safety issues. In addition, its sensitivity to ambient air leads to the severe corrosion of Li metal anode, high requirements of production and storage, and increased manufacturing cost. Plenty of efforts in recent years have overcome many bottlenecks in these fields and hastened the practical applications of high‐energy‐density LMBs. In this review, we focus on emerging methods of these two aspects to fulfill a stable and low cost electrode. In this perspective, design artificial solid electrolyte interphase (SEI) layers, construct three‐dimensional conductive current collectors, optimize electrolytes, employ solid‐state electrolytes, and modify separators are summarized to be propitious to ameliorate interfacial stability. Meanwhile, ex situ/in situ formed protective layers are highlighted in favor of heightening air stability. Finally, several possible directions for the future research on advanced Li metal anode are addressed.