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Ionic Liquids and their Polymers in Lithium‐Sulfur Batteries
Author(s) -
Josef Elinor,
Yan Yajing,
Stan Marian Cristian,
Wellmann Julia,
Vizintin Alen,
Winter Martin,
Johansson Patrik,
Dominko Robert,
Guterman Ryan
Publication year - 2019
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.201800159
Subject(s) - ionic liquid , chemistry , cathode , anode , polymer , electrolyte , polyvinylidene fluoride , battery (electricity) , lithium (medication) , chemical engineering , polymerization , inorganic chemistry , electrode , organic chemistry , catalysis , power (physics) , physics , quantum mechanics , medicine , engineering , endocrinology
Future optimized lithium‐sulfur batteries may promise higher energy densities than the current standard. However, there are many barriers which hinder their commercialization. In this review we describe how ionic liquids (ILs) and their polymers are utilized in different components of the battery to address some of these issues. For example, IL‐based electrolytes have the potential to reduce the solubility of polysulfides compared to conventional organic electrolytes. Polymerizing ILs directly on the surface of the Li‐metal anode is suggested as an approach to protect the surface of this electrode. Finally, using poly(ionic liquids) (PILs) as binders for the cathode active material may increase the performance of the cathode as compared to polyvinylidene difluoride (PVdF) and could inhibit swelling‐induced degradation. These results demonstrate the advantages of ILs and their polymers for improving the performance of Li−S batteries.