Premium
Impact of Defects on Pyrazolate Based Metal Organic Frameworks
Author(s) -
Navarro Jorge A. R.
Publication year - 2018
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.201800119
Subject(s) - chemistry , metal organic framework , metal , porosity , catalysis , conductivity , molecule , ion , nanotechnology , organic molecules , chemical physics , organic chemistry , adsorption , materials science
The high strength of the metal‐pyrazolate coordination bond allows the deliberate introduction of defects on pyrazolate based metal‐organic frameworks without affecting the integrity of the porous crystalline network. Yet the presence of defects has a major impact on the properties of these systems which include higher pore accessibility and increased interactions with guest molecules, higher ion/electronic mobility and enhanced catalytic properties. In this review selected examples of the impact of the presence of defects in the capture of environmentally relevant gases, ion and electronic conductivity and catalytic properties of defective pyrazolate based metal organic frameworks are given.