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Iron‐Catalyzed C−C Bond Formation via Chelation‐Assisted C−H Activation
Author(s) -
Yoshikai Naohiko
Publication year - 2017
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.201700047
Subject(s) - chemistry , electrophile , catalysis , reagent , heteroatom , chelation , redox , oxidative coupling of methane , oxidative addition , activation energy , medicinal chemistry , coupling reaction , photochemistry , oxidative phosphorylation , inorganic chemistry , organic chemistry , ring (chemistry) , biochemistry
This review provides a brief overview of iron‐catalyzed C−C bond forming reactions via heteroatom‐assisted C−H bond activation, which have been extensively developed in the last decade. Three major types of reactions are discussed, namely, (1) C−H activation/C−C coupling using organometallic reagents under oxidative conditions, (2) C−H activation/C−C coupling using organic electrophiles under redox‐neutral conditions, and (3) C−H activation/C−C coupling using unsaturated hydrocarbons under redox‐neutral or oxidative conditions.