Transition Metal‐Catalyzed Benzannulation towards Naturally Occurring Carbazole Alkaloids | Zendy

Zhang Xue | Zendy; Ma Shengming | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Transition Metal‐Catalyzed Benzannulation towards Naturally Occurring Carbazole Alkaloids

Author(s) -

Zhang Xue,

Ma Shengming

Publication year - 2018

Publication title -

israel journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.908

H-Index - 54

eISSN - 1869-5868

pISSN - 0021-2148

DOI - 10.1002/ijch.201700034

Subject(s) - carbazole , chemistry , regioselectivity , catalysis , scope (computer science) , carbene , transition metal , combinatorial chemistry , atom economy , annulation , substrate (aquarium) , organic chemistry , oceanography , computer science , programming language , geology

In this account, we will summarize our recent progress on development of Pt‐ or Au‐catalyzed benzannulation of 1‐indolyl‐2,3‐allenols for the efficient construction of carbazole skeleton via a metal carbene intermediate and its application towards the synthesis of naturally occurring carbazole alkaloids. The strategy enjoys the outstanding regioselectivity, atom economy, mild reaction conditions, substrate scope, functional group tolerance.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research