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Development of a Bio‐Inspired Dual Catalytic System for Alkane Dehydrogenation
Author(s) -
West Julian G.,
Sorensen Erik J.
Publication year - 2017
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.201600115
Subject(s) - dehydrogenation , chemistry , alkene , alkane , moiety , dual (grammatical number) , combinatorial chemistry , functional group , catalysis , nanotechnology , biochemical engineering , organic chemistry , art , polymer , materials science , literature , engineering
The alkene is a central functional group in organic synthesis. While myriad reliable methods exist to access this moiety from other functionalities, acceptorless dehydrogenation, or the direct synthesis of alkenes from alkanes with hydrogen gas as the sole byproduct, remains a challenging, albeit highly desirable, transformation. This essay provides an account of our recent efforts toward accessing this difficult reaction class, with particular attention paid to the diverse precedents that informed our explorations. This report highlights the benefits of maintaining a broad range of interests, and we hope that it illustrates the vast connectivity between chemical disciplines.