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1,2,3‐Triazolophanes—Cyclophanes with an Array of Molecular Structures and Supramolecular Architectures
Author(s) -
Mohan Arumugam,
Sankararaman Sethuraman
Publication year - 2012
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.201100160
Subject(s) - supramolecular chemistry , chemistry , intramolecular force , cycloaddition , azide , alkyne , click chemistry , combinatorial chemistry , nanotechnology , molecule , stereochemistry , organic chemistry , catalysis , materials science
1,2,3‐Triazolophanes are a class of cyclophanes that has attracted enormous attention in recent times. With the advent of the intramolecular copper‐mediated alkyne azide cycloaddition (CuAAC) reaction 1,2,3‐triazolophanes of various molecular structure and supramolecular architecture have been synthesized. 1,2,3‐Triazolophanes find a variety of applications as molecular hosts, ion sensors, peptidomimics, and supramolecular building blocks, among others.