Asymmetric Intermolecular Mizoroki‐Heck Reaction: From Phosphine/Phosphinite‐Nitrogen to Phosphite‐Nitrogen Ligands | Zendy

Diéguez Montserrat | Zendy; Pàmies Oscar | Zendy

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Asymmetric Intermolecular Mizoroki‐Heck Reaction: From Phosphine/Phosphinite‐Nitrogen to Phosphite‐Nitrogen Ligands

Author(s) -

Diéguez Montserrat,

Pàmies Oscar

Publication year - 2012

Publication title -

israel journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.908

H-Index - 54

eISSN - 1869-5868

pISSN - 0021-2148

DOI - 10.1002/ijch.201100100

Subject(s) - chemistry , phosphinite , phosphine , ligand (biochemistry) , intermolecular force , nitrogen , heck reaction , organic chemistry , combinatorial chemistry , catalysis , palladium , molecule , biochemistry , receptor

This review discusses the latest developments in ligand design for the Pd‐catalyzed asymmetric intermolecular Mizoroki‐Heck reaction, from the successful phosphine/phosphinite‐nitrogen ligands to the recently reported phosphite‐nitrogen ligands. The presence of a biaryl phosphite group offers several advantages as a ligand scaffold for this process.

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