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Asymmetric Intermolecular Mizoroki‐Heck Reaction: From Phosphine/Phosphinite‐Nitrogen to Phosphite‐Nitrogen Ligands
Author(s) -
Diéguez Montserrat,
Pàmies Oscar
Publication year - 2012
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.201100100
Subject(s) - chemistry , phosphinite , phosphine , ligand (biochemistry) , intermolecular force , nitrogen , heck reaction , organic chemistry , combinatorial chemistry , catalysis , palladium , molecule , biochemistry , receptor
This review discusses the latest developments in ligand design for the Pd‐catalyzed asymmetric intermolecular Mizoroki‐Heck reaction, from the successful phosphine/phosphinite‐nitrogen ligands to the recently reported phosphite‐nitrogen ligands. The presence of a biaryl phosphite group offers several advantages as a ligand scaffold for this process.