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MIL‐101 Supported Polyoxometalates: Synthesis, Characterization, and Catalytic Applications in Selective Liquid‐Phase Oxidation
Author(s) -
Maksimchuk Nataliya V.,
Kholdeeva Oxana A.,
Kovalenko Konstantin A.,
Fedin Vladimir P.
Publication year - 2011
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.201000082
Subject(s) - chemistry , catalysis , polyoxometalate , leaching (pedology) , mesoporous material , selectivity , liquid phase , characterization (materials science) , scope (computer science) , phase (matter) , heterogeneous catalysis , aqueous solution , combinatorial chemistry , aqueous two phase system , chemical engineering , organic chemistry , nanotechnology , physics , environmental science , thermodynamics , materials science , computer science , soil science , engineering , soil water , programming language
In this short review paper, we survey our recent achievements in the preparation of heterogeneous catalysts via incorporation of polyoxometalates (POMs) within cages of the mesoporous coordination polymer MIL‐101, their physicochemical characterization, and application for liquid‐phase selective oxidation of organic compounds with green oxidants — O 2 and aqueous H 2 O 2 . Special attention is paid to analyze a manifestation of confinement effects and to address the issues of catalytic activity and selectivity after immobilization and after recycling, catalyst resistance to POM leaching, and the nature of catalysis. The scope and limitations of POM/MIL‐101 catalysts are discussed.