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Miyaura Borylations of Aryl Bromides in Water at Room Temperature
Author(s) -
Lipshutz Bruce H.,
Moser Ralph,
Voigtritter Karl R.
Publication year - 2010
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.201000045
Subject(s) - aryl , catalysis , palladium , chemistry , combinatorial chemistry , polymer chemistry , organic chemistry , alkyl
New technology for palladium‐catalyzed cross‐couplings between B 2 pin 2 and aryl bromides leading to arylboronates is described. Micellar catalysis serves to enable borylations to take place in water as the only medium at ambient temperatures.