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Metal Carbonyls in Phase Transfer Catalysis
Author(s) -
Abbayes Herve Des
Publication year - 1985
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.198500104
Subject(s) - chemistry , metal carbonyl , catalysis , carbonylation , metal , organometallic chemistry , stoichiometry , phase (matter) , ligand (biochemistry) , organic chemistry , combinatorial chemistry , inorganic chemistry , carbon monoxide , biochemistry , receptor
This review is limited to phase transfer systems (solid—liquid and liquid—liquid) involving metal carbonyls. The principles of phase transfer catalysis, related to metal carbonyl properties which play a key role in these two‐phase systems, are first briefly recalled. Then, in the light of these principles, applications to inorganic chemistry (ligand exchange, preparation of metal carbonyl anions), organometallic chemistry (synthesis of π allyl complexes, clusters, orthometalated compounds, acylmetal carbonyls, complexed ylids), and finally to organic chemistry are comprehensively reviewed. In this last part, both stoichiometric and catalytic systems (with respect to the metal carbonyl) are reviewed essentially in the fields of functional reduction and carbonylation.