1,3‐Dipolar Cycloadditions of 1,1‐Difluoroallene, Nitrones, Nitrile‐Oxides and Carbonyl Ylides | Zendy

Dolbier William R. | Zendy; Burkholder Conrad R. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

1,3‐Dipolar Cycloadditions of 1,1‐Difluoroallene, Nitrones, Nitrile‐Oxides and Carbonyl Ylides

Author(s) -

Dolbier William R.,

Burkholder Conrad R.

Publication year - 1985

Publication title -

israel journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.908

H-Index - 54

eISSN - 1869-5868

pISSN - 0021-2148

DOI - 10.1002/ijch.198500080

Subject(s) - chemistry , regioselectivity , nitrile , ylide , dipole , oxide , nitrone , computational chemistry , medicinal chemistry , photochemistry , organic chemistry , cycloaddition , catalysis

The 1,3‐dipolar cycloadditions of C,N‐diphenylnitrone, C‐phenyl‐N‐methylnitrone, triphenylnitrone, mesitylnitrile oxide and tetracyanocarbonyl ylide with 1,1‐difluoroallene (DFA) are reported and discussed with respect to regiochemistry. Each of the dipoles adds exclusively to the C 2 —C 3 , non‐fluorine‐substituted π‐bond of DFA. The nitrones all undergo regiospecific reactions while mesitylnitrile oxide does not. The results are discussed with respect to FMO theory and other factors which can give rise to regiochemical variation.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research