Premium
Small Rhodium Aggregates with Unusual Oxidation States. The Synthesis and Structure of [Rh 3 ((Ph 2 PCH 2 ) 2 PPh) 2 (CO)I 4 ] [BPh 4 ] · 0.77 Acetone
Author(s) -
Balch Alan L.,
Olmstead Marilyn M.
Publication year - 1985
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.198500029
Subject(s) - rhodium , chemistry , diphosphines , acetone , catalysis , crystallography , organic chemistry
The oxidative behavior of rhodium(I) isocyanides and dimers bridged by diisocyanides and diphosphines, which leads to the formation of rhodium—rhodium bonded complexes in the +2, +5\3, +3\2 oxidation states, is reviewed. The results of an X‐ray crystallographic investigation of a new, related compound, [Rh 3 ((Ph 2 PCH 2 ) 2 ‐PPh) 2 (CO)I 4 ] [BPh 4 ] · 0.77 C 3 H 6 O, are described.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom