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Stoichiometry and Structure of the Complexes Between Lanthanide Ions and Macrocyclic Crown Ethers Containing from Four to Seven Coordinating Sites
Author(s) -
Bünzli J.C. G.,
Wessner D.
Publication year - 1984
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.198400054
Subject(s) - chemistry , lanthanide , stoichiometry , divalent , crown (dentistry) , inorganic chemistry , 15 crown 5 , polymer chemistry , crown ether , ion , organic chemistry , medicine , dentistry
The factors influencing the stoichiometry and the structure of the complexes between trivalent lanthanide perchlorates, hexafluorophosphates, nitrates, trifluoroacetates, chlorides, bromides, isothiocyanates and the polyethers 12‐crown‐4, 15‐crown‐5, 18‐crown‐6, dibenzo‐18‐crown‐6 and 21‐crown‐7 are reviewed. The properties of divalent lanthanide and Ce(IV) complexes with crown ethers are presented and discussed.