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Measurement of Absolute Propagation and Termination Rate Constants for Alkylperoxyls in Solution by the Hydroperoxide Method
Author(s) -
Howard J. A.
Publication year - 1984
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.198400006
Subject(s) - chemistry , reaction rate constant , work (physics) , kinetic energy , absolute (philosophy) , thermodynamics , alkyl , constant (computer programming) , phase (matter) , kinetics , organic chemistry , classical mechanics , programming language , physics , computer science , philosophy , epistemology
Kinetic and product studies of liquid phase autoxidations in the presence of high concentrations of alkyl hydroperoxides have enabled absolute propagation and termination rate constants for alkylperoxyls to be measured. A large number of rate constants and activation parameters have been accumulated over the past few years by this technique and the highlights of this work are presented in this review.