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The Perimeter Model and Magnetic Circular Dichroism of Aceheptylene
Author(s) -
Wallace Susan L.,
Michl Josef
Publication year - 1980
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.198000080
Subject(s) - perimeter , chemistry , magnetic circular dichroism , circular dichroism , mixing (physics) , interpretation (philosophy) , nuclear magnetic resonance , crystallography , geometry , physics , quantum mechanics , spectral line , mathematics , computer science , programming language
The use of the perimeter model for the interpretation of magnetic circular dichroism of aromatic molecules is briefly reviewed. The model is applied to a rather difficult case, aceheptylene, whose electronic states are only distantly related to those of its perimeter. Correct signs are still predicted for the effects of magnetic L 1 – L 2 and B 1 ‐ B 2 mixing.