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The Configurational Stability of Triorganostannyl‐Transition Metal Compounds
Author(s) -
Gielen Marcel,
Eynde Ivan Vanden
Publication year - 1980
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.198000057
Subject(s) - chemistry , diastereomer , epimer , manganese , cobalt , coalescence (physics) , transition metal , computational chemistry , metal , stereochemistry , organic chemistry , catalysis , physics , astrobiology
The configurational stability of triorganostannyl–iron, –manganese and –cobalt complexes has been determined by studying the coalescence of the NMR signals of diastereotopic groups and by looking at the epimerization of diastereomeric mixtures of these compounds. Possible substitution reactions, transforming the studied derivatives into one another, have been checked.