Matrix Effects on Size‐Selectivity of Polymeric Reagents and Catalysts | Zendy

Regen Steven L. | Zendy; Lee Dan P. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Matrix Effects on Size‐Selectivity of Polymeric Reagents and Catalysts

Author(s) -

Regen Steven L.,

Lee Dan P.

Publication year - 1978

Publication title -

israel journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.908

H-Index - 54

eISSN - 1869-5868

pISSN - 0021-2148

DOI - 10.1002/ijch.197800051

Subject(s) - selectivity , chemistry , reagent , catalysis , phosphine , triphenylphosphine , alkyl , polymer , tris , organic chemistry , matrix (chemical analysis) , combinatorial chemistry , polymer chemistry , chromatography , biochemistry

Selectivity has been investigated for the catalytic hydrogenation of alkenes using a polymeric catalyst derived from a polystyryldiphenylphosphine resin and tris(triphenylphosphine)chlororhodium (I). These data together with the selectivity observed for a closely related polymeric phosphine reagent capable of converting alcohols to alkyl chlorides provide compelling evidence that a polymer support can impose a modest degree of size‐selectivity to an attached reagent and catalyst.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research