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A Graphite Supported Chiral Catalyst
Author(s) -
Kagan H. B.,
Yamagishi T.,
Motte J. C.,
Setton R.
Publication year - 1978
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.197800049
Subject(s) - chemistry , hydrosilylation , moiety , rhodium , catalysis , aldehyde , enantioselective synthesis , asymmetric hydrogenation , organic chemistry , graphite , chirality (physics) , polymer chemistry , chiral anomaly , physics , fermion , quantum mechanics , nambu–jona lasinio model
Partially graphitized carbons were functionalized by carboxylic groups which were esterified with 4‐hydroxybenzaldehyde. A chiral diphosphine moiety, analogous to the DIOP framework, was then synthesized from the aldehyde function. The supported chiral diphosphine was transformed into a rhodium catalyst. Preliminary results of asymmetric hydrogenation or asymmetric hydrosilylation are described.
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