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On Some New Oxidation—Reduction Polymers
Author(s) -
Manecke Georg,
Ehrenthal Einhart,
Finck Wilhelm,
Wunsch Friedrich
Publication year - 1978
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.197800046
Subject(s) - redox , chemistry , reagent , polymer , benzotriazole , reusability , combinatorial chemistry , reducing agent , half reaction , chemical engineering , polymer chemistry , organic chemistry , software , computer science , engineering , programming language
Redox polymers are among the most well‐documented polymer reagents, and tailored redox polymers are obtainable. The synthesis and the redox properties of some new silica‐anchored quinones are described. A high redox reaction velocity was found with a modified pore‐controlled glass. Polymer reagents with N‐chlorobenzotriazole units were obtained from suitable benzotriazole derivatives or by polymer‐analogous reactions starting from p ‐aminostyrene polymers. With these products chlorinations as well as mild oxidation reactions were performed with good yields. Reusability and mechanical properties were good.