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Oxygen Exchange Reactions of Cationic Carbonyl Derivatives of Manganese and Rhenium with H 2 18 O and Related Processes
Author(s) -
Darensbourg Donald J.
Publication year - 1976
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.197600044
Subject(s) - chemistry , rhenium , metal carbonyl , oxygen , manganese , cationic polymerization , metal , medicinal chemistry , oxygen atom , group (periodic table) , group 2 organometallic chemistry , inorganic chemistry , photochemistry , organic chemistry , molecule
Reactions proposed to involve the intermediacy of metal species containing the hydroxycarbonyl group, [M—COOH], are reviewed. Particular attention is given to reversible reactions of Group VIIb metal carbonyl derivatives with isotopically labelled water, which presumably proceeds via a [M—COOH] intermediate, to afford oxygen labelled metal carbonyl derivatives. The current status of the scope and mechanistic details of this oxygen‐exchange reaction is summarized.