Premium
Studies of the Cis, Cis ‐Cyclodeca‐1,6‐Diene System
Author(s) -
Shani Ar
Publication year - 1975
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.197500006
Subject(s) - chemistry , diene , decalin , bicyclic molecule , bromine , halogenation , medicinal chemistry , quinone , stereochemistry , organic chemistry , catalysis , natural rubber
In the course of attempting to synthesize cyclodeca‐1,6‐diyne (IIIa) from cis, cis ‐cyclodeca‐1,6‐diene (XIX) derivatives by a successive bromination and dehydrobromination, transannular addition of one mole of bromine to the diene system occurred. The reaction products were bicyclic decalin derivatives. New symmetric and unsymmetric derivatives of XIX were prepared. Various approaches towards obtaining [10]annulene‐quinone (XXIX) are reported.