Ortho Effects. I. The Mechanisms of the H 3 O and CH 3 O 2  Elimination from the Molecular Ion of N‐Methyl  Ortho ‐Nitro‐ Para ‐Toluidine | Zendy

Zaretskii Zeev V. I. | Zendy; Amit Boaz | Zendy; Patchornik Avraham | Zendy

Premium

Ortho Effects. I. The Mechanisms of the H 3 O and CH 3 O 2 Elimination from the Molecular Ion of N‐Methyl Ortho ‐Nitro‐ Para ‐Toluidine

Author(s) -

Zaretskii Zeev V. I.,

Amit Boaz,

Patchornik Avraham

Publication year - 1974

Publication title -

israel journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.908

H-Index - 54

eISSN - 1869-5868

pISSN - 0021-2148

DOI - 10.1002/ijch.197400088

Subject(s) - chemistry , nitro , methyl group , deuterium , ion , ring (chemistry) , polyatomic ion , medicinal chemistry , group (periodic table) , stereochemistry , organic chemistry , alkyl , quantum mechanics , physics

The molecular ion of the N‐methyl ortho ‐nitro‐ para ‐toluidine (I) readily eliminates H 3 O. The sources of the H atoms lost were proved by deuterium labeling to be an HNCH 3 group as well as, probably, the C‐methyl group of the aromatic ring. The interaction between the N‐methyl and nitro groups in I also leads to the expulsion of CH 3 O 2 from the molecular ion.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research