Preparation and Crystal Structures of Some Compounds of the A 3  BX 5  Type (A = Cs, Tl, NH 4 , B = Mn, Fe, Co, X = Cl, Br) | Zendy

Amit M. | Zendy; Horowitz Zodkevitz A. | Zendy; Ron E. | Zendy; Makovsky J. | Zendy

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Preparation and Crystal Structures of Some Compounds of the A 3 BX 5 Type (A = Cs, Tl, NH 4 , B = Mn, Fe, Co, X = Cl, Br)

Author(s) -

Amit M.,

Horowitz Zodkevitz A.,

Ron E.,

Makovsky J.

Publication year - 1973

Publication title -

israel journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.908

H-Index - 54

eISSN - 1869-5868

pISSN - 0021-2148

DOI - 10.1002/ijch.197300074

Subject(s) - isostructural , chemistry , orthorhombic crystal system , tetragonal crystal system , crystallography , crystal structure , group (periodic table) , space group , inorganic chemistry , x ray crystallography , diffraction , organic chemistry , physics , optics

The compounds Cs 3 FeBr 5 , Cs 3 MnBr 5 ,Tl 3 FeCl 5 , Tl 3 CoCl 5 , (NH 4 ) 3 FeCl 5 and (NH 4 ) 3 CoCl 5 were prepared and their crystal structures determined. Cs 3 FeBr 5 , Cs 3 MnBr 5 , Tl 3 FeCl 5 and Tl 3 CoCl 5 belong to the tetragonal system, space group 14/mcm, isostructural with Cs 3 CoCl 5 [1]. (NH 4 ) 3 FeCl 5 and (NH 4 ) 3 CoCl 5 belong to the orthorhombic system, space group Pnma, isostructural with (NH 4 ) 3 ZnCl 5 [2].

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