Proton Transfer in Liquid Ammonia Solutions Containing Water and Hydroxide Ion | Zendy

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Proton Transfer in Liquid Ammonia Solutions Containing Water and Hydroxide Ion

Author(s) -

Marks Stephen B.

Publication year - 1973

Publication title -

israel journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.908

H-Index - 54

eISSN - 1869-5868

pISSN - 0021-2148

DOI - 10.1002/ijch.197300046

Subject(s) - chemistry , hydroxide , ammonia , proton , ion , inorganic chemistry , reaction rate constant , liquid ammonia , analytical chemistry (journal) , kinetics , chromatography , organic chemistry , physics , quantum mechanics

The rate of proton transfer in ammonia solutions containing water and hydroxide ion was determined as a function of temperature and concentration by means of PMR spectroscopy. A first order dependence on hydroxide ion and second order dependence on water concentration was found with a rate constant of k 3 = 6.1 ± 1.2 × 10 3 M −2 sec −1 at 25°C and ΔE ‡ = 4.5 ± 0.5 kcal/mole. The value of k 3 is in good agreement with that reported by other workers.

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